ETHANOL PRODUCER'S DATA BASE

Simplicity in Applied technology

Hydrometer : Triple Scale  

The triple scale hydrometer is used to check for sugar content of the beer, as well as to define   the potential alcohol content of the fermented beer, as well as to check the finished beer alcohol content, based on a simple formula. See: Calculate Alcohol content of fermentation.

 

 

A hydrometer is an instrument whose function is based on

Archimedes principle. 

This principle states that a body (the hydrometer) immersed

in a fluid is buoyed up by a force equal to the weight of the displaced fluid. 

The hydrometer measures the weight of the liquid displaced by the volume of the hydrometer.

 

Specific Gravity is a dimensionless unit defined as the ratio of density of the material to the density of water. 

                         Water =1 g/cm3

                 Specific Gravity = Density g/cm3 

                                                1 g/cm3

    

 

The greater the density, the tighter or closer the molecules are packed inside the substance.

Therefore, the greater the density / specific gravity of a liquid the higher a hydrometer will be buoyed by it.

Sugar Adds waight to water therefore the numbers will be POSITIVE with respect to water 

 

 

 

 

 

 

Calculate alcohol content of fermentation 

  • To determine the amount of alcohol in the beer:
    • Compare the specific gravity of the beer before it starts fermenting
    • To its specific gravity when it is finished fermenting.
  •  The specific gravity is a measure of the density of a liquid relative to water.
  • The density of water is 1 kilogram per liter,
  • So if the specific gravity of a liquid is 1.06, one liter of that liquid will weigh 1.06 kg
    • The liquid that will form the beer is called a wort (pronounced wert).
    • Its specific gravity is always higher than water because it contains a lot of dissolved sugars.
    • Yeast added to the wort will convert some of these dissolved sugars into ethyl alcohol.
    • When the beer is finished, the specific gravity is always less than when it started, because some of the sugars have been converted into alcohol, which is less dense than water (0.79 kg/L).
  •  Glucose, C6H12O6 is the main sugar that will be converted to alcohol.
  • Many reactions take place inside the yeast that ultimately convert:
    • Each glucose molecule into two molecules of ethyl alcohol: CH3CH2OH
    • And two molecules of carbon dioxide: CO².
      • This is the reason why we get as much CO² as we get Ethanol 
        •  
          • C6H12O6 => 2(CH3CH2OH) + 2(CO2)

 If you check the periodic table, you can figure out the molecular weights of these two molecules.

  • The molecular weight of ethyl alcohol is 46.0688
  • And the molecular weight of carbon dioxide is 44.0098.
    • You will need these numbers to calculate the alcohol content of the beer.

 

During the fermentation process most of the carbon dioxide that forms from the reaction bubbles out of the solution and leaves the fermentation vessel by way of a vent.

You can say that all of it leaves, because the amount the remains in the beer is very small compared to the amount that leaves.

 

If you look at the equation for the reaction you see that each glucose is split into two ethyl alcohol molecules and two carbon dioxide molecules.

 

That means for each carbon dioxide molecule that leaves the fermentation vessel, one ethyl alcohol molecule must be formed inside the vessel.

 

  • If you look back at the molecular weights you can say that for each:
    • 44.0098 grams of CO2 that leaves the vessel
    • 46.0688 grams of Ethyl alcohol are formed.
    • Put another way, for each gram of CO2 that bubbles off...
    • 1.05 grams of ethyl alcohol are produced 

  • To calculate an approximate alcohol by volume of your finished Ethanol
    • Take the Original gravity
    • Less the Final Gravity
    • Multiply by129 
  • For example, a Mash with an original gravity of 1.050
  • And a final gravity of 1.015 would be calculated as follows:
    •  1.050 -1.015 = 0.035 X 129 = 4.51%  ABV

  • Take your Original Gravity reading at the very start of fermentation.
  • Final Gravity reading is taken just before distilling.
  • A Mash with an Original Gravity of 1.060 will end with a Final Gravity of:1.015-1.020.
  • Water has a specific gravity of 1.000 
  • Most hydrometers are calibrated at 60F, so you may have to adjust the gravity readings      by using the table below.
  • "Hydrometer Temperature Correction factors"

Alcohol hydrometer 

  • Tralles' hydrometer scale
    • A hydrometer scale calibrated so that readings are the percentage of ethanol (ethyl alcohol) by volume. 
    • Zero on the scale is the level to which the instrument sinks in pure water at 60°F,
    • 100 is the level to which it sinks in pure ethanol at 60°F.
      • It was used in Germany and in the U. S. Customs Service.

 

Alcohol Proof

  • When the Proof of an alcohol solution is used, one is dealing with a solution of mainly ethanol: CH3CH2OH and some water.
  • The value of the Proof is exactly twice the percentage of alcohol in the solution.
  • Pure alcohol is 200 Proof.  
    • A solution that is 50% alcohol would be 100 Proof.

 

  • The proof is determined using a hydrometer.
    • As the percentage of alcohol in a solution increases,
    • The density decreases because alcohol has a lower density that water.
    • The hydrometer is a floating device that has a long stem that sticks out of the solution and its larger base, has its bottom filled with just the right amount of balast to sink at a precise rate and level.
    • As the density of the solution decreases the hydrometer sinks further into the liquid.
    • The amount of the stem that sticks out of the solution is a measure of the proof, Te neck of the stem has a printed scale, calibrated to indicate the correct proof.

 

  • Origins of the term Proof 
  • The term originated in the 18th century, when payments to British sailors included rations of rum.
  • To ensure that it hadn't been watered down, the rum was “proved” by dousing gunpowder in it, then testing to see if it would ignite.
  • If the gunpowder didn't burn, the rum contained too much water—and was considered to be “underproof.” 
  • A “proven” sample of rum was defined to be 100 degrees proof.
  • This was later found to occur at 57.15% ethanol.
  • This percentage is very close to a 4:7 ratio of alcohol to total amount of liquid.
  • Seventy degrees proof is then equivalent to 40% ABV [(4÷7)× .7 = 0.4].
    • And pure, 100% alcohol is 175 degrees proof   [(4÷7)× 1.75 = 1.0].
    • This definition is no longer used in the United Kingdom

*The ABV system must be used to state the alcohol content on bottles.

Reading a Hydrometer

  • Fill your hydrometer jar about ¾ with the liquid /alcohol you wish to test. 
  • Insert the hydrometer slowly. 
  • Spin gently with your thumb and index finger, to release bubbles if any have formed.
  • Allow hydrometer to rest.
  • Find the plane of the liquid surface.
  • Eye horizontal to this plane. 
  • Read at the plane cutting the hydrometer scale.
  • Courtesy of:

Hydrometer Scales

Tralle and Proof Scale

The Tralle scale indicates directly in percent ethyl alcohol by weight in water from 0 to 100%     The Proof scale indicates the proof of alcohol from 0 to 200, at 60°F.

American Petroleum Institute & ASTM The AP1 scale was selected in 1921 by the American Petroleum Institute; the United States Bureau of Mines; and the National Institute of Standards and Technology as the standard for petroleum products in the United States.
Baumé ScaleThe Baumé scale is used for liquids heavier than water such as syrups. The scale was originally proposed by Antoine Baumé, a French chemist, in 1768. The scale has been widely accepted because of the simplicity of the numerals which represent liquid specific gravity. 

Brix & Balding

 
The Brix scale is used almost exclusively by the sugar industry. Degrees on the scale are equal to the percentage of sucrose by weight at a standard temperature. 
The Balling scale is used mainly in the brewing industry to estimate percent wort but is also used to indicate percent by weight of either dissolved solids or sugar liquors. The hydrometers are graduated in percent weight at 14° Réaumur (17.5°C).
Specific Gravity

Specific gravity hydrometers measure the ratio of the density of a sample compared to the density of pure water at the same temperature.  The specified temperature for these types of hydrometers is 60/60°F (15.6/15.6°C).

Twaddle

The Twaddle scale is the result of attempting to simplify the measurement of industrial liquids heavier than water. The range of specific gravity from 1.000 to 2.000 is divided into 200 equal parts. Thus 1° Twaddle equals 0.005 specific gravity.

Hydrometer Temperature Correction Factors

   Temperature °F

 Temperature °C

 Correction Factor

 60°F

16°C 

0.0 

 70°F

21°C 

+0.001 

 77°F

25°C 

+0.002 

 84°F

29°C 

+0.003 

 95°F

35°C 

+0.005 

 105°F

 41°C

 +0.007