- The "p" in pH is always written as lower case, not upper case.
- The "p" stands for potential. The "H" stands for Hydrogen.
- pH of a fermentation will go more acidic as the ferment progresses due to yeast metabolism byproducts being excreted into the fermenting solution.
- For this reason, we in the beverage brewing/distilling world start our fermentations at the range of
- pH 5 - pH 5.5 so that when finished, the pH will still be around pH 4 which ensures we don't stop or retard the yeast action too soon ( i.e. before all the sugars are converted to ethanol & CO2 ).
- pH scale is an inverse logarithmic representation of Hydrogen-Ion ( H+ ) concentration in a solution.
- Each individual pH unit is a factor of 10 different than the next higher or lower unit.
- This means that pH 6.0 is 10 times ( 10 x 1 ) more acidic than pH 7.0,
- and pH 5.0 is 100 times ( 10 x 10 ) more acidic than pH 7.0.
- Given all of the above, it is clear that the correct pH conditions (slightly acid) of fermentations at start will retard bacterial growth, allowing a correct yeast growth & metabolism environment and ensure virtually trouble-free progress to completion.
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- The pH is a measure of the acidity or alkalinity of an aqueous solution expressed on a scale of 1-14.
- Neutral is pH 7, pH 1-7 is acid, and pH 7-14 is alkaline.
- The pH is measured with an electronic pH meter or test papers that change color according to the pH of the solution being tested.
- These meters and papers are available from swimming pool supply houses, garden shops, and laboratory supply companies.
- Control of pH during the mashing and fermentation process is important for two reasons:
- The growth of harmful bacteria is retarded by acid solutions.
- Yeast will grow only in a mildly acid solution.
- Ideal pH level during fermentation is absolutely essential.
- When pH drops below about 4.2 all fermentation stops.
- Yeast needs a slightly acid environment in order to grow.
- So, for best results pH should be kept between 4.8 and 5.0.
- Most grain mashes have a naturally acid pH of between 5.4 and 5.6 after conversion has been accomplished.
- Other materials, notably saccharine substances like molasses and fruit pressings, have a naturally alkaline pH and must be acidified prior to fermentation.
- The principal bacterial contaminants in a distillery are those that form lactic acid.
- Although the production of fuel alcohol is not concerned with the taste of the product,
- Lactic acid formed subtracts from the yield of alcohol.
- The production of lactic acid and other contaminants should therefore be avoided as much as possible.
- Below about 4.1 to 4.4 is detrimental to other processes taking place during fermentation.
- The development of these micro-organisms is severely repressed at pH values under 5.0.
- Above 5.0 their growth is rapid.
- The optimum pH range then is 4.8 to 5.0.
- Consequently, the pH should be checked during the cooking and conversion.
- LOWERING pH: If it is above 5.0, it should be reduced by the addition of acid.
- The acid most commonly used is sulfuric, although any mineral acid is perfectly suitable.
- Hydrochloric (muriatic) acid, for example, is available from swimming pool suppliers.
- The acid should be added cautiously, the mash stirred, and the pH checked.
- RAISING pH: To raise the pH, use with sodium hydroxide caustic soda or ordinary lime.
- CAUTION: Do not over correct, or you may have to scrap the mash.